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Nitric Acid — Part 2: Oxidising and acidic properties, and tests

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Lesson

Two personalities

Part 2 — Nitric acid behaves both as an acid (it gives H⁺ ions) and as an oxidising agent (it gives oxygen). Which one wins depends on the concentration and on what it meets.

In this lesson you will

  • Explain why nitric acid is a strong oxidising agent
  • Write equations for concentrated and dilute nitric acid with copper, and for the concentrated acid with carbon and sulphur
  • Explain why only very dilute nitric acid gives hydrogen, and with which metals
  • Write equations for nitric acid with bases, carbonates, hydrogen carbonates and sulphites, and describe tests for the acid
Table of the two kinds of behaviour of nitric acid with typical reactions and products
BehaviourTypical reactionUsual products
Oxidising agentWith copper, carbon, sulphurA nitrate or oxide, water and NO₂ or NO
AcidWith bases, carbonates, sulphitesA nitrate, water (and CO₂ or SO₂)
Acid giving hydrogenOnly very dilute acid with Mg or MnA nitrate and hydrogen