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Spectrum — Notes

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1. Dispersion of white light

  • Dispersion: the splitting of white light into its constituent colours by a prism. The band of colours is the spectrum: violet, indigo, blue, green, yellow, orange, red (VIBGYOR).
  • Cause: in a material medium, light of different colours travels at different speeds, so the refractive index depends on wavelength: μviolet>μred\mu_{violet} > \mu_{red}. Hence violet is deviated most and red least.
  • In vacuum all colours travel at the same speed, 3×1083 \times 10^{8} m s⁻¹.
  • A prism only separates colours already present; a second, identical prism placed inverted recombines them into white light.
  • Monochromatic light (one wavelength, for example a sodium lamp) is deviated but not dispersed.
Table comparing red and violet light in glass
ColourSpeed in glassμ in glassDeviation
RedHighestLeastLeast
VioletLowestGreatestGreatest

Formulas

  • Refractive index depends on colour
    μ=cv,μviolet>μred\mu = \frac{c}{v}, \quad \mu_{violet} > \mu_{red}

Key terms

Dispersion

The splitting of white light into its constituent colours on passing through a prism.

Spectrum

The band of colours obtained when white light is dispersed.

Monochromatic light

Light of a single wavelength (single colour).

2. The visible spectrum

  • Wavelength range about 400 nm (violet) to 700–800 nm (red); 1 nm=10−91\ \text{nm} = 10^{-9} m.
  • Order of increasing wavelength: violet, indigo, blue, green, yellow, orange, red; frequency increases the other way (c=fλc = f\lambda).
  • Colour is decided by frequency, which does not change on refraction.
Table of wavelength and frequency of violet, green and red light
ColourWavelength (about)Frequency (about)
Violet400 nm7.5 × 10¹⁴ Hz
Green530 nm5.7 × 10¹⁴ Hz
Red700 nm4.3 × 10¹⁴ Hz

Formulas

  • Wave equation for light
    c=fλc = f \lambda

Key terms

Wavelength

The distance between two successive crests (or compressions) of a wave.

3. The electromagnetic spectrum

RegionWavelength (about)Source or use
Gamma raysbelow 10⁻¹¹ mRadioactive nuclei; cancer treatment
X-rays10⁻¹¹ to 10⁻⁸ mFast electrons hitting a metal; bone images
Ultraviolet10⁻⁸ to 4 × 10⁻⁷ mSun, arcs; sterilising
Visible4 × 10⁻⁷ to 8 × 10⁻⁷ mSun, lamps; seeing
Infrared8 × 10⁻⁷ to 10⁻³ mHot bodies; remote controls
Microwaves10⁻³ to 0.3 mOvens, radar, mobile phones
Radio wavesabove 0.3 mBroadcasting

Common properties: produced by accelerated charges; transverse electric and magnetic fields; travel in vacuum at 3×1083 \times 10^{8} m s⁻¹; obey c=fλc = f\lambda; not deflected by electric or magnetic fields; can be reflected and refracted; carry energy.

Table showing the two ends of the electromagnetic spectrum
OrderIncreasing wavelengthIncreasing frequency
FirstGamma raysRadio waves
LastRadio wavesGamma rays

Key terms

Electromagnetic wave

A transverse wave of changing electric and magnetic fields that can travel through vacuum at the speed of light.

4. Infrared and ultraviolet radiation

Infrared (IR): beyond red. Produced by hot bodies (Sun, heater, human body). Detected by a thermopile or blackened-bulb thermometer. Properties: strong heating effect; less scattered by haze and fog; absorbed by water vapour and CO₂; reflected by polished surfaces. Uses: remote controls, night vision and thermal cameras, haze photography, physiotherapy, drying paint, weather satellites, greenhouses.

Ultraviolet (UV): beyond violet. Produced by the Sun, electric arcs, mercury vapour lamps (quartz tubes). Detected by photographic film and fluorescence (zinc sulphide). Properties: causes fluorescence; kills germs; causes chemical changes (tanning); absorbed by ordinary glass, transmitted by quartz; absorbed by the ozone layer. Uses: sterilising water and instruments, checking forged notes, vitamin D formation. Harmful in excess: sunburn, eye damage, skin cancer.

Table comparing infrared and ultraviolet radiation
FeatureInfraredUltraviolet
PositionBeyond redBeyond violet
DetectorThermopileFluorescent screen, film
GlassPartly transmittedAbsorbed (quartz transmits)
Main effectHeatingChemical, germicidal

Key terms

Thermopile

A detector of infrared radiation that produces a current when warmed by the radiation.

Fluorescence

The emission of visible light by a substance while ultraviolet radiation falls on it.

5. Scattering of light

  • Scattering: absorption and re-emission of light in all directions by small particles.
  • For particles much smaller than the wavelength (air molecules): scattered intensity ∝1λ4\propto \dfrac{1}{\lambda^{4}}. Blue is scattered about 5 times as much as red.
  • Blue sky: air molecules scatter blue most; skylight is mainly blue.
  • Red Sun at sunrise and sunset: long path through air removes blue by scattering; red reaches the eye.
  • Red danger signals: red is scattered least and penetrates fog farthest.
  • White clouds: large droplets scatter all colours equally.
  • Black sky in space or on the Moon: no atmosphere, no scattering.
Table of four scattering effects and their reasons
ObservationReason
Blue skyBlue scattered most
Red sunriseBlue scattered out on a long path
Red signalsRed scattered least
White cloudsLarge drops scatter all colours

Formulas

  • Scattering by very small particles
    Iscattered∝1λ4I_{\text{scattered}} \propto \frac{1}{\lambda^{4}}

Key terms

Scattering of light

The process by which small particles absorb light and send it out again in all directions.

Exam tips

Common mistakes

  • Saying red is deviated (or scattered) most.
  • Saying the prism “produces” colours.
  • Mixing up the order of the electromagnetic spectrum, especially X-rays and gamma rays, or infrared and microwaves.
  • Forgetting that ordinary glass absorbs ultraviolet.
  • Explaining the red sunrise without mentioning the longer path through air.

How marks are usually awarded

  • Dispersion: definition (1), cause — μ depends on wavelength (1), order of deviation (1).
  • IR and UV: each property or use 1 mark; a named detector or source earns credit.
  • Scattering: name the particles, the wavelength dependence and the conclusion.