1. The nucleus; Z, A and isotopes
Nucleus: protons (+1, ~1 u) and neutrons (0, ~1 u). Atomic number = number of protons; mass number = protons + neutrons; neutrons . Notation .
Isotopes: same , different (different numbers of neutrons); same chemical properties. Examples: protium, deuterium, tritium (, , ); carbon-12 and carbon-14.
| Nuclide | Protons | Neutrons |
|---|---|---|
| Na-23 | 11 | 12 |
| Co-60 | 27 | 33 |
| C-14 | 6 | 8 |
Formulas
- Number of neutrons
Key terms
- Atomic number
The number of protons in the nucleus of an atom.
- Mass number
The total number of protons and neutrons in the nucleus.
- Isotopes
Atoms of the same element with the same atomic number but different mass numbers.
2. Radioactivity and the three radiations
Radioactivity: spontaneous disintegration of unstable nuclei, emitting α, β or γ radiation; not affected by temperature, pressure or chemical state.
| Property | α | β | γ |
|---|---|---|---|
| Nature | Helium nucleus | Fast electron (from nucleus) | Electromagnetic wave |
| Charge | +2e | −e | 0 |
| Mass | 4 u | ≈ 1/1840 u | 0 |
| Speed | ≈ 0.1c | up to 0.99c | c |
| Ionising power | Highest | Medium | Lowest |
| Penetrating power | Lowest (paper) | Medium (few mm Al) | Highest (cm of lead) |
| In electric field | Towards − plate | Towards + plate (more) | Undeflected |
| Radiation | Stopped by |
|---|---|
| α | Paper |
| β | Aluminium (few mm) |
| γ | Lead (several cm) |
Key terms
- Radioactivity
The spontaneous disintegration of the nucleus of an unstable atom with the emission of alpha, beta or gamma radiation.
- Ionising power
The ability of radiation to knock electrons out of atoms of a gas.
3. Changes in the nucleus
- α decay: , : .
- β decay: a neutron becomes a proton + electron; unchanged, : .
- γ emission: no change in or (the nucleus loses excess energy).
- In every equation, totals of and of balance on both sides.
| Emission | ΔA | ΔZ |
|---|---|---|
| α | −4 | −2 |
| β | 0 | +1 |
| γ | 0 | 0 |
Formulas
- Alpha decay
- Beta decay
Key terms
- Alpha decay
Emission of an alpha particle, which lowers the mass number by 4 and the atomic number by 2.
- Beta decay
Emission of an electron from the nucleus, which raises the atomic number by 1 and leaves the mass number unchanged.
4. Uses, hazards and safety
Uses: Co-60 (radiotherapy), I-131 (thyroid), Na-24 (blood circulation studies), P-32 (tracer in agriculture), C-14 (dating), γ sources (sterilising instruments, checking welds, pipe leaks), β sources (thickness gauges).
Harmful effects: burns, radiation sickness, cancer (leukaemia), genetic mutations.
Background radiation: cosmic rays, radioactive rocks and soil, radon gas, K-40 in food and the body, medical X-rays, fallout.
Safety: long tongs, lead containers and aprons, distance, short exposure time, film badges (dosimeters), no eating near sources. X-rays are also ionising; radioactive fallout is radioactive dust spread by nuclear explosions or accidents.
| Isotope | Use |
|---|---|
| Co-60 | Cancer therapy |
| I-131 | Thyroid |
| C-14 | Dating |
Key terms
- Background radiation
Low-level radiation always present in the environment from natural and man-made sources.
- Radioisotope
A radioactive isotope of an element.
5. Fission, fusion and nuclear waste
Fission: a heavy nucleus splits into two lighter nuclei when struck by a slow neutron, releasing energy and 2–3 neutrons; chain reaction (controlled in reactors, uncontrolled in atom bombs). .
Fusion: light nuclei join to form a heavier nucleus at extremely high temperatures, releasing energy (Sun, stars, hydrogen bomb). .
Energy comes from a loss of mass (). Nuclear waste: cool in ponds, seal in glass/steel and concrete, store deep underground; it remains radioactive for thousands of years.
| Fission | Fusion |
|---|---|
| Heavy splits | Light join |
| Reactors | Sun |
Formulas
- Mass–energy equivalence
Key terms
- Nuclear fission
The splitting of a heavy nucleus into two lighter nuclei with the release of energy.
- Nuclear fusion
The joining of light nuclei to form a heavier nucleus with the release of energy.
- Chain reaction
A self-sustaining series of fissions in which neutrons from one fission cause further fissions.
Exam tips
Common mistakes
- Saying β particles come from the electron shells.
- Getting the change in Z wrong for β decay.
- Confusing fission (splitting) with fusion (joining).
- Forgetting the neutrons when balancing fission equations.
How marks are usually awarded
- Decay equations (1–2 marks): correct A and Z, symbol of the radiation.
- Comparisons (1 mark per property).
- Uses and safety (1 mark each): named isotope or precaution with a reason.