1. Free electrons, drift and mobility
- Current (A = C s⁻¹); conventional current is opposite to electron flow.
- Free electrons move randomly (~10⁵ m s⁻¹) colliding with ions; relaxation time τ = mean time between collisions (~10⁻¹⁴ s).
- In a field: acceleration ; drift velocity (opposite to E), ~10⁻⁴ m s⁻¹. Mobility (m² V⁻¹ s⁻¹).
- (n = free electrons per m³): all electrons within of a section cross it in .
- Lamps light instantly because the field is set up along the wire at nearly the speed of light.
Formulas
- Current and drift
- Drift velocity
Key terms
- Relaxation time
Average time between successive collisions of a free electron with the ions.
- Drift velocity
Average velocity acquired by free electrons in a conductor in an electric field.
- Mobility
Drift velocity per unit electric field, eτ/m.
2. Ohm’s law in microscopic form
- Current density (A m⁻²). With : .
- Conductivity ; resistivity .
- For a wire, , give with : Ohm’s law (V ∝ I at constant temperature).
Formulas
- Ohm’s law (vector form)
- Resistivity
Key terms
- Current density
Current per unit cross-sectional area, J = I/A.
3. Resistance, resistivity and V–I graphs
- ; conductance (S); conductivity (S m⁻¹).
- Stretching to times the length at constant volume: , .
- Ohmic: V–I graph a straight line through the origin (metals at constant temperature). Non-ohmic: curved (filament lamp), one-way (diode), negative slope regions, or different in reverse.
- metal wire at constant temperature: ohmic (R = 4 Ω)
- filament lamp: non-ohmic, R rises as it heats
Formulas
- Resistance of a wire
Key terms
- Resistivity
Resistance of a conductor of unit length and unit cross-section; a property of the material.
- Ohmic conductor
One for which V is proportional to I at constant temperature.
4. Temperature dependence
- Metals: , α > 0 (copper about 3.9 × 10⁻³ °C⁻¹): n constant, τ decreases as ions vibrate more.
- Semiconductors: ρ decreases with temperature (negative α): n increases sharply, outweighing the fall in τ.
- Alloys (manganin, constantan): very small α, high ρ — standard resistors; nichrome for heaters.
- copper (metal): rises almost linearly
- semiconductor: falls steeply
Formulas
- Temperature dependence
Key terms
- Temperature coefficient of resistivity
Fractional change in resistivity per degree rise in temperature.
5. Electrical energy and power
- ; energy ; Joule heating .
- Commercial unit: 1 kW h (one “unit”) = J. Bill = total kW h × rate.
- Rated appliance: ; on a different supply .
- Long-distance transmission at high voltage reduces current and so the loss.
- metal wire at constant temperature: ohmic (R = 4 Ω)
- filament lamp: non-ohmic, R rises as it heats
Formulas
- Electrical power
Key terms
- Kilowatt hour
Energy used by a 1 kW device in one hour, 3.6 × 10⁶ J.
Exam tips
- Derive and ρ = m/(ne²τ); convert mm² to m².
- Stretching: constant volume, R ∝ l².
- Temperature: explain through n and τ.
- Power: choose the form using the common quantity; bills in kW h.