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Rate of Reaction and Rate Laws

Chemistry · Chapter 5 · Physical Chemistry (Units 1-3: Solutions, Electrochemistry, Chemical Kinetics)

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Your path through this chapter

  1. Notes Beta

    6 sections with key terms, formulas and exam tips.

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  2. Flashcards Beta

    31 cards for quick recall of key terms and facts.

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  3. Practice

    61 board-style questions with instant checks: Multiple choice 22, Short answer 16, Assertion and reason 5, Long answer 5.

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  4. Chapter test Free

    Short and long chapter tests in board pattern, with results and analysis.

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Topics 6

  1. Scope of chemical kinetics; slow and fast reactions explained by bonds; average and instantaneous rate (graphical)
  2. Factors affecting rate: nature of reactants, surface area, concentration, temperature, catalyst and radiation; law of mass action and active mass
  3. Rate law and rate constant; order of reaction as an experimental quantity; units of k
  4. Zero order reactions: rate equation and units
  5. First order reactions: derivation of the integrated rate equation; half-life; independence of k from initial concentration
  6. Molecularity; elementary and complex reactions; mechanism and rate-determining step; order versus molecularity