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Haloarenes

Chemistry · Chapter 13 · Organic Chemistry (Units 6-10: Haloalkanes and Haloarenes to Biomolecules)

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  1. Notes Beta

    5 sections with key terms, formulas and exam tips.

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  3. Practice

    67 board-style questions with instant checks: Multiple choice 26, Short answer 17, Assertion and reason 5, Long answer 5.

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Topics 5

  1. Nature of the C-X bond in haloarenes; preparation by Sandmeyer and Gattermann reactions and by electrophilic substitution
  2. Physical properties of haloarenes
  3. Electrophilic substitution (chlorination, nitration, sulphonation) with mechanism; ortho-para directing influence of halogen
  4. Nucleophilic substitution (replacement of Cl by -OH and -NH2) with mechanism; reduction to benzene
  5. Wurtz-Fittig and Fittig reactions; Grignard reagent formation; structure and effects of DDT