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Molecular Orbital Theory, Coordinate Bonds, Resonance and Hydrogen Bonding

Chemistry · Chapter 9 · Physical Chemistry (Units 1-2 and 4-7: Basic Concepts, Atomic Structure, Bonding, Thermodynamics, Equilibrium, Redox)

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Topics 5

  1. Molecular orbital theory (qualitative) for homonuclear diatomic molecules from H2 to Ne2: bonding and antibonding orbitals, energy level diagrams, bond order
  2. Paramagnetism of O2; relative stabilities of O2, O2-, O2 2-, O2+ and of N2, N2+, N2-, N2 2-
  3. Coordinate (dative) bond: ammonium and hydronium ions, oxyacids of chlorine, nitric acid, ozone
  4. Resonance in ozone, carbon dioxide, carbonate ion and nitrate ion
  5. Hydrogen bonding: conditions, intermolecular (HF, water and ice, ethanol) and intramolecular