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Aromatic Hydrocarbons: Benzene

Chemistry · Chapter 24 · Organic Chemistry (Units 8-9: Basic Principles and Techniques, Hydrocarbons)

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Topics 5

  1. Aromatic compounds: IUPAC nomenclature; structure of benzene, Kekule resonance structures; aromaticity
  2. Preparation of benzene from sodium benzoate and from phenol; physical properties
  3. Electrophilic substitution with mechanism: halogenation, nitration, sulphonation, Friedel-Crafts alkylation and acylation
  4. Directive influence of substituents in monosubstituted benzene (ortho/para and meta directors)
  5. Oxidation, reaction with ozone, addition of hydrogen, chlorine and bromine; pyrolysis to biphenyl; carcinogenicity, toxicity and uses