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Entropy, Free Energy and Spontaneity

Chemistry · Chapter 12 · Physical Chemistry (Units 1-2 and 4-7: Basic Concepts, Atomic Structure, Bonding, Thermodynamics, Equilibrium, Redox)

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Topics 4

  1. Inadequacy of the first law; spontaneous and non-spontaneous processes; second law of thermodynamics
  2. Entropy: physical significance, state function; second law in terms of entropy; entropy change of the universe; thermal death
  3. Gibbs and Helmholtz free energy and their relationship; criteria for spontaneity using delta G = delta H - T delta S
  4. Relation between standard free energy change and equilibrium constant; third law of thermodynamics (statement)